Periodic
table of the
elements. Marked in red are the elements (more than 40) for which the
Mössbauer
effect has been observed. The most prominent “Mössbauer
nuclide” is 57Fe.
More than 90 % of the nearby 50 000 publications which have appeared so
far
refer to 57Fe isotope. Nuclides suitable for Mössbauer
spectroscopy
should possess excited nuclear states with lifetimes in the range of
ca. 10-6
to ca. 10-11 s, and transition energies between ca. 5 and
180 keV.
Longer (shorter) lifetimes than indicated lead, according to the
Heisenberg
Uncertainty Principle, to too narrow (broad) emission and absorption
lines,
which no longer effectively overlap. Transition energies beyond ca. 180
keV
cause too large recoil effects which destroy the resonance (see next
figure).
Gamma quanta with energies smaller than ca. 5 keV will mostly be
absorbed in
the source and absorber material.
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